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New page: left|200px<br /><applet load="2fad" size="450" color="white" frame="true" align="right" spinBox="true" caption="2fad, resolution 1.600Å" /> '''Crystal structure o...
 
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[[Image:2fad.gif|left|200px]]<br /><applet load="2fad" size="450" color="white" frame="true" align="right" spinBox="true"
caption="2fad, resolution 1.600&Aring;" />
'''Crystal structure of E. coli heptanoyl-ACP'''<br />


==Overview==
==Crystal structure of E. coli heptanoyl-ACP==
A knowledge of the structures of acyl chain loaded species of the acyl, carrier protein (ACP) as used in fatty acid biosynthesis and a range of, other metabolic events, is essential for a full understanding of the, molecular recognition at the heart of these processes. To date the only, crystal structure of an acylated species of ACP is that of a butyryl, derivative of Escherichia coli ACP. We have now determined the structures, of a family of acylated E. coli ACPs of varying acyl chain length. The, acyl moiety is attached via a thioester bond to a phosphopantetheine, linker that is in turn bound to a serine residue in ACP. The growing acyl, chain can be accommodated within a central cavity in the ACP for transport, during the elongation stages of lipid synthesis through changes in the, conformation of a four alpha-helix bundle. The results not only clarify, the means by which a substrate of varying size and complexity is, transported in the cell but also suggest a mechanism by which interacting, enzymes can recognize the loaded ACP through recognition of surface, features including the conformation of the phosphopantetheine linker.
<StructureSection load='2fad' size='340' side='right'caption='[[2fad]], [[Resolution|resolution]] 1.60&Aring;' scene=''>
== Structural highlights ==
<table><tr><td colspan='2'>[[2fad]] is a 2 chain structure with sequence from [https://en.wikipedia.org/wiki/Escherichia_coli Escherichia coli]. Full crystallographic information is available from [http://oca.weizmann.ac.il/oca-bin/ocashort?id=2FAD OCA]. For a <b>guided tour on the structure components</b> use [https://proteopedia.org/fgij/fg.htm?mol=2FAD FirstGlance]. <br>
</td></tr><tr id='method'><td class="sblockLbl"><b>[[Empirical_models|Method:]]</b></td><td class="sblockDat" id="methodDat">X-ray diffraction, [[Resolution|Resolution]] 1.6&#8491;</td></tr>
<tr id='ligand'><td class="sblockLbl"><b>[[Ligand|Ligands:]]</b></td><td class="sblockDat" id="ligandDat"><scene name='pdbligand=NA:SODIUM+ION'>NA</scene>, <scene name='pdbligand=PM5:S-(2-{[N-(2-HYDROXY-4-{[HYDROXY(OXIDO)PHOSPHINO]OXY}-3,3-DIMETHYLBUTANOYL)-BETA-ALANYL]AMINO}ETHYL)+HEPTANETHIOATE'>PM5</scene>, <scene name='pdbligand=ZN:ZINC+ION'>ZN</scene></td></tr>
<tr id='resources'><td class="sblockLbl"><b>Resources:</b></td><td class="sblockDat"><span class='plainlinks'>[https://proteopedia.org/fgij/fg.htm?mol=2fad FirstGlance], [http://oca.weizmann.ac.il/oca-bin/ocaids?id=2fad OCA], [https://pdbe.org/2fad PDBe], [https://www.rcsb.org/pdb/explore.do?structureId=2fad RCSB], [https://www.ebi.ac.uk/pdbsum/2fad PDBsum], [https://prosat.h-its.org/prosat/prosatexe?pdbcode=2fad ProSAT]</span></td></tr>
</table>
== Function ==
[https://www.uniprot.org/uniprot/ACP_ECOLI ACP_ECOLI] Carrier of the growing fatty acid chain in fatty acid biosynthesis.[HAMAP-Rule:MF_01217]
== Evolutionary Conservation ==
[[Image:Consurf_key_small.gif|200px|right]]
Check<jmol>
  <jmolCheckbox>
    <scriptWhenChecked>; select protein; define ~consurf_to_do selected; consurf_initial_scene = true; script "/wiki/ConSurf/fa/2fad_consurf.spt"</scriptWhenChecked>
    <scriptWhenUnchecked>script /wiki/extensions/Proteopedia/spt/initialview03.spt</scriptWhenUnchecked>
    <text>to colour the structure by Evolutionary Conservation</text>
  </jmolCheckbox>
</jmol>, as determined by [http://consurfdb.tau.ac.il/ ConSurfDB]. You may read the [[Conservation%2C_Evolutionary|explanation]] of the method and the full data available from [http://bental.tau.ac.il/new_ConSurfDB/main_output.php?pdb_ID=2fad ConSurf].
<div style="clear:both"></div>
<div style="background-color:#fffaf0;">
== Publication Abstract from PubMed ==
A knowledge of the structures of acyl chain loaded species of the acyl carrier protein (ACP) as used in fatty acid biosynthesis and a range of other metabolic events, is essential for a full understanding of the molecular recognition at the heart of these processes. To date the only crystal structure of an acylated species of ACP is that of a butyryl derivative of Escherichia coli ACP. We have now determined the structures of a family of acylated E. coli ACPs of varying acyl chain length. The acyl moiety is attached via a thioester bond to a phosphopantetheine linker that is in turn bound to a serine residue in ACP. The growing acyl chain can be accommodated within a central cavity in the ACP for transport during the elongation stages of lipid synthesis through changes in the conformation of a four alpha-helix bundle. The results not only clarify the means by which a substrate of varying size and complexity is transported in the cell but also suggest a mechanism by which interacting enzymes can recognize the loaded ACP through recognition of surface features including the conformation of the phosphopantetheine linker.


==About this Structure==
Structural studies of fatty acyl-(acyl carrier protein) thioesters reveal a hydrophobic binding cavity that can expand to fit longer substrates.,Roujeinikova A, Simon WJ, Gilroy J, Rice DW, Rafferty JB, Slabas AR J Mol Biol. 2007 Jan 5;365(1):135-45. Epub 2006 Sep 23. PMID:17059829<ref>PMID:17059829</ref>
2FAD is a [http://en.wikipedia.org/wiki/Single_protein Single protein] structure of sequence from [http://en.wikipedia.org/wiki/Escherichia_coli Escherichia coli] with NA, ZN and PM5 as [http://en.wikipedia.org/wiki/ligands ligands]. Full crystallographic information is available from [http://ispc.weizmann.ac.il/oca-bin/ocashort?id=2FAD OCA].


==Reference==
From MEDLINE&reg;/PubMed&reg;, a database of the U.S. National Library of Medicine.<br>
Structural studies of fatty acyl-(acyl carrier protein) thioesters reveal a hydrophobic binding cavity that can expand to fit longer substrates., Roujeinikova A, Simon WJ, Gilroy J, Rice DW, Rafferty JB, Slabas AR, J Mol Biol. 2007 Jan 5;365(1):135-45. Epub 2006 Sep 23. PMID:[http://ispc.weizmann.ac.il//pmbin/getpm?pmid=17059829 17059829]
</div>
<div class="pdbe-citations 2fad" style="background-color:#fffaf0;"></div>
 
==See Also==
*[[Acyl carrier protein|Acyl carrier protein]]
*[[Acyl carrier protein 3D structures|Acyl carrier protein 3D structures]]
== References ==
<references/>
__TOC__
</StructureSection>
[[Category: Escherichia coli]]
[[Category: Escherichia coli]]
[[Category: Single protein]]
[[Category: Large Structures]]
[[Category: Roujeinikova, A.]]
[[Category: Roujeinikova A]]
[[Category: NA]]
[[Category: PM5]]
[[Category: ZN]]
[[Category: acyl carrier protein]]
[[Category: acyl chain binding]]
[[Category: fatty acid biosynthesis]]
 
''Page seeded by [http://ispc.weizmann.ac.il/oca OCA ] on Wed Nov 21 10:27:07 2007''

Latest revision as of 07:58, 30 October 2024

Crystal structure of E. coli heptanoyl-ACP

2fad, resolution 1.60Å

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