Fischer projection: Difference between revisions

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The Fischer projection is a two-dimensional representation of a linear monosaccharide showing the stereochemistry.
The Fischer projection is a two-dimensional representation of a linear monosaccharide showing the stereochemistry. The figure below shows - from left to right - (a) glucose in a relaxed conformation, (b) glucose in a conformation where the carbon chain is in an all-syn conformation, (c) the wedge-and-dashes representation with the carbon chain on the vertical axis and (d) the Fischer projection. This image is from https://commons.wikimedia.org/wiki/File:Fischer_projection_-_projection_of_D-glucose.png
 


[[Image:Fischer projection - projection of D-glucose.png|500px]]
[[Image:Fischer projection - projection of D-glucose.png|500px]]




More text
<Structure load='' size='350' frame='true' align='right' caption='Insert caption here' scene='85/856021/Centeredc2/1' />
 
The coordinates of glucose are from https://sites.science.oregonstate.edu/~gablek/CH334/Chapter5/fischer.htm.
 
<jmol>
<jmolLink>
  <script> moveto 1.0 { 511 -545 664 171.11} 133.56 0.0 0.0 {-0.43 -1.4969999999999999 -0.31} 4.711404157531831 {0 0 0} 0 0 0 3.0 0.0 0.0;
  </script>
  <text>carbon 1 (not chiral)</text>
</jmolLink>
</jmol>
 
<jmol>
<jmolLink>
  <script> moveto 1.0 { 421 -394 817 166.63} 133.56 0.0 0.0 {0.395 -1.242 0.9540000000000001} 4.711404157531831 {0 0 0} 0 0 0 3.0 0.0 0.0;
  </script>
  <text>carbon 2</text>
</jmolLink>
</jmol>
 
<jmol>
<jmolLink>
  <script> moveto 1.0 { -1 -48 999 165.59} 133.56 0.0 0.0 {0 0 1.749} 4.711404157531831 {0 0 0} 0 0 0 3.0 0.0 0.0;
  </script>
  <text>carbon 3</text>
</jmolLink>
</jmol>
 
<jmol>
<jmolLink>
  <script> moveto 1.0 { -421 403 813 166.5} 133.56 0.0 0.0 {-0.395 1.242 0.9540000000000001} 4.711404157531831 {0 0 0} 0 0 0 3.0 0.0 0.0;
  </script>
  <text>carbon 4</text>
</jmolLink>
</jmol>


<Structure load='' size='350' frame='true' align='right' caption='Insert caption here' scene='85/856021/Centeredc2/1' />
<jmol>
<jmolLink>
  <script> moveto 1.0 { -236 -719 -654 132.38} 133.56 0.0 0.0 {0.427 1.496 -0.305} 4.711404157531831 {0 0 0} 0 0 0 3.0 0.0 0.0;
  </script>
  <text>carbon 5</text>
</jmolLink>
</jmol>


<scene name='85/856021/Centeredc2/1'>Center on carbon number 2</scene>
<jmol>
<jmolLink>
  <script> moveto 1.0 { -245 -922 300 163.36} 133.56 0.0 0.0 {-0.115 0.754 -1.525} 4.711404157531831 {0 0 0} 0 0 0 3.0 0.0 0.0;
  </script>
  <text>carbon 6 (not chiral)</text>
</jmolLink>
</jmol>