2q0m: Difference between revisions
New page: left|200px<br /><applet load="2q0m" size="350" color="white" frame="true" align="right" spinBox="true" caption="2q0m, resolution 1.70Å" /> '''Tricarbonylmanganese... |
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==Overview== | ==Overview== | ||
The reaction of the new and structurally characterized covalent | The reaction of the new and structurally characterized covalent {Mn(CO)(3)(H(2)O)(2)}(+)-lysozyme adduct with NiS(4) and NiN(2)S(2) complexes generates binuclear Ni-Mn complexes; relevance to the reactivity of the protein-bound {Fe(CO)(CN)(2)} intermediate during maturation of [NiFe] hydrogenases is discussed. | ||
==About this Structure== | ==About this Structure== | ||
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[[Category: Cavazza, C.]] | [[Category: Cavazza, C.]] | ||
[[Category: Fontecave, M.]] | [[Category: Fontecave, M.]] | ||
[[Category: Fontecilla-Camps, J | [[Category: Fontecilla-Camps, J C.]] | ||
[[Category: Oudart, Y.]] | [[Category: Oudart, Y.]] | ||
[[Category: Razavet, M.]] | [[Category: Razavet, M.]] | ||
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[[Category: tricarbonyl manganese(i)]] | [[Category: tricarbonyl manganese(i)]] | ||
''Page seeded by [http://oca.weizmann.ac.il/oca OCA ] on | ''Page seeded by [http://oca.weizmann.ac.il/oca OCA ] on Thu Feb 21 18:34:53 2008'' | ||
Revision as of 16:34, 21 February 2008
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Tricarbonylmanganese(I)-lysozyme complex : a structurally characterized organometallic protein
Overview
The reaction of the new and structurally characterized covalent {Mn(CO)(3)(H(2)O)(2)}(+)-lysozyme adduct with NiS(4) and NiN(2)S(2) complexes generates binuclear Ni-Mn complexes; relevance to the reactivity of the protein-bound {Fe(CO)(CN)(2)} intermediate during maturation of [NiFe] hydrogenases is discussed.
About this Structure
2Q0M is a Single protein structure of sequence from Gallus gallus with CL, NA, MN, CMO and TFS as ligands. Active as Lysozyme, with EC number 3.2.1.17 Full crystallographic information is available from OCA.
Reference
Tricarbonylmanganese(I)-lysozyme complex: a structurally characterized organometallic protein., Razavet M, Artero V, Cavazza C, Oudart Y, Lebrun C, Fontecilla-Camps JC, Fontecave M, Chem Commun (Camb). 2007 Jul 19;(27):2805-7. Epub 2007 Jun 11. PMID:17609782
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