User:Wayne Decatur/mof dev: Difference between revisions
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JARMEU - a metal-organic framework | |||
<StructureSection load='1d66' size='500' frame='true' side='right' caption='A Metal–organic framework structure: the CSD entry WUTXUH' scene='10/1092924/Csd_entry_wutxuh_basics/2' > | |||
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==Background== | |||
Metal-organic frameworks have been shown to be applicable to catalysis, among many other applications, as [[Proteopedia:Hot_News|highlighted three chemists doing seminal work in this field being awarded the Nobel Prize in Chemistry in 2025]]. | |||
JARMEU... | |||
Here the crystal structure of JARMEU metal-organic framework is featured. | |||
==A catalytic molybdenum metal-organic framework== | |||
<jmol> | |||
<jmolCheckbox> | |||
<scriptWhenChecked>select all; spacefill on;</scriptWhenChecked> | |||
<scriptWhenUnchecked>select all; spacefill 0.35; select hydrogen; spacefill 0.25;</scriptWhenUnchecked> | |||
<checked>false</checked> | |||
<!-- <checked></checked> set it to false or delete it or comment it out as <checked>false</checked> or <checked> </checked>still show as checked--> | |||
<text>CPK Spacefll mode</text> | |||
</jmolCheckbox> | |||
</jmol> | |||
<!--<scene name='70/701975/1d66_firstglance_secondary/2'>Each monomer</scene> of the protein dimer has 3 '''<font color='#f00080'> alpha helices</font>'''. | |||
The protein <scene name='70/701975/1d66_firstglance/2'>binds as a dimer to a symmetrical 17-base-pair sequence</scene>. Specifically, the consensus Gal4p-binding site is a 17-mer of sequence conforming to the motif below, which has the key feature of CGG triplets at the 5' ends, separated by 11 bps, or 5′-CGG-N11-CCG-3′.<br> | |||
<br>--> | |||
<!--<span style="font-weight: bold;font-family: Courier New; font-size: 14pt">--> | |||
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<span style="background:black;color:#FFC0C8">5'-CGGNNNNNNNNNNNCCG-3'</span><br> | |||
<font style='background:black;color:#ffffff;'>|||||||||||||||||</font><br> | |||
<span style="background:black;color:#FFFF80">3'-CGGNNNNNNNNNNNGGC-5'</span></span>--> | |||
<br/> | |||
<scene name='10/1092924/Csd_entry_wutxuh_set/4'>The CSD entry WUTXUH as a 1x1x3 set of the metal organic framework</scene>. | |||
<scene name='10/1092924/Csd_entry_wutxuh_plane/4'>The CSD entry WUTXUH as a plane of the metal organic framework</scene>. | |||
<jmol> | |||
<jmolButton> | |||
<script>load /wiki/scripts/10/1092924/Csd_entry_wutxuh_basics/2.spt</script> | |||
<text>Restore Default Scene</text> | |||
</jmolButton> | |||
</jmol> | |||
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</StructureSection> | |||
==Technical Details== | |||
The views featuring the 1x1x3 set and the plane were built using [https://chemapps.stolaf.edu/jmol/jsmol/jcse/explore.htm the Jmol Crystal Symmetry Explorer] to examine [https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=WUTXUH&DatabaseToSearch=CSD CSD Entry: WUTXUH]. | |||
==Reference== | |||
<ref group="xtra">PMID: 32744270</ref><references group="xtra"/> | |||
==See also== | |||
* [[Metal-Ligand Polyhedra]] | |||
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A catalytic molybdenum metal-organic framework | A catalytic molybdenum metal-organic framework | ||
