2eb9: Difference between revisions

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[[Image:2eb9.jpg|left|200px]]
{{Seed}}
[[Image:2eb9.png|left|200px]]


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{{STRUCTURE_2eb9|  PDB=2eb9  |  SCENE=  }}  
{{STRUCTURE_2eb9|  PDB=2eb9  |  SCENE=  }}  


'''Crystal Structure of Cu(II)(Sal-Leu)/apo-Myoglobin'''
===Crystal Structure of Cu(II)(Sal-Leu)/apo-Myoglobin===




==Overview==
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apo-Myoglobin (apo-Mb) was reconstituted with three copper complexes: CuII(Sal-Phe) (1; Sal-Phe = N-salicylidene-L-phenylalanato), CuII(Sal-Leu) (2; Sal-Leu = N-salicylidene-L-leucinato), and CuII(Sal-Ala) (3; Sal-Ala = N-salicylidene-L-alanato). The crystal structures of 1.apo-Mb (1.65 Angstrom resolution) and 2.apo-Mb (1.8 Angstrom resolution) show that the coordination geometry around the CuII atom in apo-Mb is distorted square-planar with tridentate Sal-X and a Nepsilon atom of His64 in the apo-Mb cavity and the plane of these copper complexes is perpendicular to that of heme. These results suggest that the apo-Mb cavity can hold metal complexes with various coordination geometries.
The line below this paragraph, {{ABSTRACT_PUBMED_17523632}}, adds the Publication Abstract to the page
(as it appears on PubMed at http://www.pubmed.gov), where 17523632 is the PubMed ID number.
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{{ABSTRACT_PUBMED_17523632}}


==About this Structure==
==About this Structure==
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[[Category: Yamane, T.]]
[[Category: Yamane, T.]]
[[Category: Oxygen storage/transport]]
[[Category: Oxygen storage/transport]]
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