Sulfite Oxidase: Difference between revisions
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== Tryptophan's Importance in Sulfite Oxidase == | |||
Tryptophan has been shown as a crucial amino acid that can facilitate electron transfer. A paper written by Shih C (Shih C, Museth AK, Abrahamsson M, Blanco-Rodriguez AM, Di Bilio AJ, Sudhamsu J, Crane BR, Ronayne KL, Towrie M, Vlcek A Jr, Richards JH, Winkler JR, Gray HB. Science. 2008. 320, 1760-1762.) suggests that multi-step electron tunneling can enhance charge transfer rates, in which redox active amino acid side chains act as intermediate donors or acceptors. | Tryptophan has been shown as a crucial amino acid that can facilitate electron transfer. A paper written by Shih C (Shih C, Museth AK, Abrahamsson M, Blanco-Rodriguez AM, Di Bilio AJ, Sudhamsu J, Crane BR, Ronayne KL, Towrie M, Vlcek A Jr, Richards JH, Winkler JR, Gray HB. Science. 2008. 320, 1760-1762.) suggests that multi-step electron tunneling can enhance charge transfer rates, in which redox active amino acid side chains act as intermediate donors or acceptors. | ||
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[[Image:Sulfite-oxidase-active-site-500w.jpg]] | [[Image:Sulfite-oxidase-active-site-500w.jpg]] | ||
== References == | |||
Shih C, Museth AK, Abrahamsson M, Blanco-Rodriguez AM, Di Bilio AJ, Sudhamsu J, Crane BR, Ronayne KL, Towrie M, Vlcek A Jr, Richards JH, Winkler JR, Gray HB. Science. 2008. 320, 1760-1762. | |||
Feng C, Tollin G, Enemark JH. Biochim Biophys Acta. 2007. 1774(5), 527-539. | |||
[[http://www.chem.arizona.edu/enemark/new/]] | |||