2q0m | pdb_00002q0m

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Tricarbonylmanganese(I)-lysozyme complex : a structurally characterized organometallic protein

File:2q0m.jpg


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2q0m, resolution 1.70Å
Ligands: CL, NA, MN, CMO and TFS
Activity: Lysozyme, with EC number 3.2.1.17
Coordinates: save as pdb, mmCIF, xml



Overview

The reaction of the new and structurally characterized covalent {Mn(CO)(3)(H(2)O)(2)}(+)-lysozyme adduct with NiS(4) and NiN(2)S(2) complexes generates binuclear Ni-Mn complexes; relevance to the reactivity of the protein-bound {Fe(CO)(CN)(2)} intermediate during maturation of [NiFe] hydrogenases is discussed.

About this Structure

2Q0M is a Single protein structure of sequence from Gallus gallus. Full crystallographic information is available from OCA.

Reference

Tricarbonylmanganese(I)-lysozyme complex: a structurally characterized organometallic protein., Razavet M, Artero V, Cavazza C, Oudart Y, Lebrun C, Fontecilla-Camps JC, Fontecave M, Chem Commun (Camb). 2007 Jul 19;(27):2805-7. Epub 2007 Jun 11. PMID:17609782

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