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User:Wayne Decatur/mof dev

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==See also==
==See also==
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* [[A catalytic molybdenum metal-organic framework]]
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* [[Metal-Ligand Polyhedra]]
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-----------------------
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A catalytic molybdenum metal-organic framework
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<StructureSection load='1d66' size='500' frame='true' side='right' caption='A Metal–organic framework structure: the CSD entry WUTXUH' scene='10/1092924/Csd_entry_wutxuh_basics/2' >
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<!-- important to note you need to use 'side' in a StructureSection instead of 'align'. If you leave 'align' it doesn't work.-->
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==Background==
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Metal-organic frameworks have been shown to be applicable to catalysis, among many other applications, as [[Proteopedia:Hot_News|highlighted three chemists doing seminal work in this field being awarded the Nobel Prize in Chemistry in 2025]].
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A catalytic molybdenum metal-organic framework was synthesized from porphyrin and sodium molybdate dihydrate by a hydrothermal method.<br/>
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The framework was characterized and shown to catalyze oxidation of cyclohexene.<br/>
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Here the crystal structure of catalytic molybdenum metal-organic framework is featured.
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==A catalytic molybdenum metal-organic framework==
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<jmol>
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<jmolCheckbox>
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<scriptWhenChecked>select all; spacefill on;</scriptWhenChecked>
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<scriptWhenUnchecked>select all; spacefill 0.35; select hydrogen; spacefill 0.25;</scriptWhenUnchecked>
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<checked>false</checked>
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<!-- <checked></checked> set it to false or delete it or comment it out as <checked>false</checked> or <checked> </checked>still show as checked-->
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<text>CPK Spacefll mode</text>
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</jmolCheckbox>
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</jmol>
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<!--<scene name='70/701975/1d66_firstglance_secondary/2'>Each monomer</scene> of the protein dimer has 3 '''<font color='#f00080'> alpha helices</font>'''.
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The protein <scene name='70/701975/1d66_firstglance/2'>binds as a dimer to a symmetrical 17-base-pair sequence</scene>. Specifically, the consensus Gal4p-binding site is a 17-mer of sequence conforming to the motif below, which has the key feature of CGG triplets at the 5' ends, separated by 11 bps, or 5′-CGG-N11-CCG-3′.<br>
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&nbsp;<br>-->
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<!--<span style="font-weight: bold;font-family: Courier New; font-size: 14pt">-->
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<!-- By setting font to courier, I can use non-proportional font. Whereas by default, rest of Proteopedia is proportional
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&nbsp;&nbsp;<span style="background:black;color:#FFC0C8">5'-CGGNNNNNNNNNNNCCG-3'</span><br>&nbsp;&nbsp;
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&nbsp;&nbsp;<font style='background:black;color:#ffffff;'>|||||||||||||||||</font><br>
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&nbsp;&nbsp;<span style="background:black;color:#FFFF80">3'-CGGNNNNNNNNNNNGGC-5'</span></span>-->
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<br/>
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<scene name='10/1092924/Csd_entry_wutxuh_set/4'>The CSD entry WUTXUH as a 1x1x3 set of the metal organic framework</scene>.
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<scene name='10/1092924/Csd_entry_wutxuh_plane/4'>The CSD entry WUTXUH as a plane of the metal organic framework</scene>.
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<jmol>
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<jmolButton>
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<script>load /wiki/scripts/10/1092924/Csd_entry_wutxuh_basics/2.spt</script>
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<text>Restore Default Scene</text>
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</jmolButton>
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</jmol>
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<!--
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<br/>
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<br/>
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<br/>
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<br/>
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-->
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</StructureSection>
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==Technical Details==
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The views featuring the 1x1x3 set and the plane were built using [https://chemapps.stolaf.edu/jmol/jsmol/jcse/explore.htm the Jmol Crystal Symmetry Explorer] to examine [https://www.ccdc.cam.ac.uk/structures/Search?Ccdcid=WUTXUH&DatabaseToSearch=CSD CSD Entry: WUTXUH].
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==Reference==
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<ref group="xtra">PMID: 32744270</ref><references group="xtra"/>
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==See also==
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* [[Metal-Ligand Polyhedra]]
* [[Metal-Ligand Polyhedra]]

Revision as of 19:32, 9 October 2025

A Metal–organic framework structure: the CSD entry JARMEU

Drag the structure with the mouse to rotate

Technical Details

The views featuring the 1x1x3 set and the plane were built using the Jmol Crystal Symmetry Explorer to examine CSD Entry: JARMEU.

References

  1. ↑ https://www.nobelprize.org/uploads/2025/10/advanced-chemistryprize2025.pdf

See also

Proteopedia Page Contributors and Editors (what is this?)

Wayne Decatur

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